Experiment 14: Determination of an Equilibrium Constant

J— — Experiment 14: Determination of an Equilibrium Constant Objectives: To study the chemical reaction of Fe3+ and SCN- to produce Fe(SCN)2+ in aqueous solution. To measure concentrations of ions in solution using a spectrophotometer. To determine the equilibrium constant of this reaction at a given temperature. Procedure: Part 1: Calibration Curve Using Standard Solutions (Done with a group) 1. Obtain seven clean 150 mL beakers, one beaker per person. 2. Prepare solutions A-1 to A-7 in each beaker, each person preparing one solution. 3.Once all the solutions are prepared, set the wavelength of the spectrophotometer to 450nm. 4. Obtain a cuvette and fill it about half way with solution A-1, the blank sample. Insert the cuvette carefully, as to not get any fingerprints on the sides, into the spectrophotometer and zero the instrument. This will be the only time the spectrophotometer needs to be zeroed. 5. Pour out solution A-1, rinse the cuvette twice with A-2, and recor d the absorbance for A-2. Do this for the subsequent solutions. 6. Plot the data, absorbance versus concentration.This will be the calibration curve used for Part 2. Part 2: Solutions to Determine the Equilibrium Constant, K 1. Obtain 5 clean 50 mL beakers and prepare solutions B-1 to B-5. 2. Follow steps 3-5 from Part 1, using B-1 as the new blank. 3. Using the calibration curve from Part 1, determine the equilibrium concentration of [Fe(SCN) 2+] from the absorbance measured for B-1 to B-5. Data Tables: Part 1 Solutions for Calibration Curve Solution| 0. 200M Fe(NO3) 3| 0. 00200M KSCN| 0. 1M HNO3| [Fe(SCN) 2+]| Absorption| A-1| 25. 0 mL| 0. 00 mL| 75. mL| 0 M| 0. 000| A-2| 25. 0 mL| 1. 00 mL| 74. 0 mL| 2 x 10-5 M| 0. 097| A-3| 25. 0 mL| 2. 00 mL| 73. 0 mL| 4 x 10-5 M| 0. 160| A-4| 25. 0 mL| 4. 00 mL| 71. 0 mL| 8 x 10-5 M| 0. 335| A-5| 25. 0 mL| 6. 00 mL| 69. 0 mL| 1. 2 x 10-4 M| 0. 532| A-6| 25. 0 mL| 8. 00 mL| 67. 0 mL| 1. 6 x 10-4 M| 0. 684| A-7| 25. 0 mL| 10. 00 mL| 65. 0 mL| 2. 0 x 10-4 M| 0. 843| Part 2 Solutions for the Determination of the Equilibrium Constant Solution| 0. 200M Fe(NO3) 3| 0. 00200M KSCN| 0. 1M HNO3| Absorption Measured| [Fe(SCN) 2+] From Calibration Curve| B-1| 5. mL| 1. 00 mL| 5. 00 mL| 0. 113| 2. 67 x 10-5 M| B-2| 5. 0 mL| 2. 00 mL| 4. 00 mL| 0. 260| 6. 06 x 10-5 M| B-3| 5. 0 mL| 3. 00 mL| 3. 00 mL| 0. 397| 9. 28 x 10-5 M| B-4| 5. 0 mL| 4. 00 mL| 2. 00 mL| 0. 521| 1. 22 x 10-4 M| B-5| 5. 0 mL| 5. 00 mL| 1. 00 mL| 0. 614| 1. 44 x 10-4 M| Questions: 1. a. If K >>1 then the equilibrium will lie to the right, favoring the products. At equilibrium there will be very little reactant and mostly product present. b. If K

Airline industry analysis by Porter’s Five Forces Essay

The Airline industry provides a very unique service to its customers. It transports people with a high level of convenience and efficiency that cannot not be provided by any other industry or substitute. Airline companies pride themselves on the way they treat their customer during the flight. They have things such as food, drinks, entertainment, and a welcoming staff. The service of transportation is provided in other industries but the airline surpasses all of them when it comes to timeliness. The geographic scope of the airline industry is at a global level. Some firms are able to fly their planes all over the world while others focus on smaller geographic areas. The five forces model is one way to answer the first basic question in strategic management; â€Å"Why are some industries more attractive than others?† This model shows the five forces that shape industry competition; threat of new entrants, bargaining power of buyers, threat of substitutes, bargaining power of suppliers, and competitors. In order to analyze the airline industry we have look at each of these forces. Bargaining power of Buyers The airline industry is made up of two groups of buyers. First, there are individual flyers. They buy plane tickets for a number of reasons that can be personal or business related. This group is extremely diverse; most people in developed countries have purchased a plane ticket. They can do this through the specific airline or through the second group of buyers; travel agencies and online portals. This buyer group works as a middle man between the airlines and the flyers. They work with multiple airline firms in order to give customers the best flight possible. Between these two groups there is definitely a large amount of buyers compared to the number of firms. There are low switching costs between firms because many people choose the flight based on where they are going and the cost at the time. This is some loyalty to firms but not enough for high switching costs. Each customer needs a lot of important information. They need to know the details of what  is provided during the flight. Buyers need to understand the timing of the flight and the safety aspects of flying in general. The service provided is unique. Each airline has a niche. Some airlines focus on cost, while others focus on having the best amenities, etc. Overall the bargaining power of buyers has an extremely low threat in this industry. Bargaining Power of Suppliers Next we look at the bargaining power of the suppliers. In this case the major suppliers are the airplane manufacturers. The top two manufacturers in the world currently are Boeing and Airbus(Odell,Mark). In this industry the inputs are extremely standardized. Airline companies only seem to differentiate with amenities. The planes are very similar. Currently some manufacturers are trying to make their plans more ecofriendly. Airline companies cannot easily switch suppliers. Most firms have long term contracts with their suppliers. Planes are such high capital products that firms probably make long term loan agreements and have more favorable credit terms when they don’t switch companies. It is difficult to enter into the plane manufacturing industry because of the capital needed to enter. The amount of money and expertise needed to make even one plane is around 200 million dollars. For this reason there are very few suppliers in the airline industry. Airline firms are the only source of income for these manufacturers so their business is extremely important. Based on these things the bargaining power of suppliers has a low threat as well. Threat of New Entrants Threat of new entrants is another major aspect of the five forces. This aspect has a low threat for the airline industry. There are two aspects that do however raise the threat level. First, there are extremely low switching costs. Second, there are no proprietary products or services involved. Even with these two aspects the industry still has a very low threat overall. Existing firms have a large cost advantage. This industry requires  a large amount of capital and without a strong customer base there will be little to no profit in the first few years. Existing firms can and will use their high capital to retaliate against newer firms with whatever means necessary such as lowering prices and taking a loss. Although there are low switching costs between brands, consumers tend to only chose well-known names. Airline tickets are expensive so people don’t want to give that money to firms they don’t trust. There is also a huge safety aspect involved and most consumers feel safer with firms that have been around for a long period of time. This industry requires plane and flying experience which also lowers the threat of entry. When firms decide to enter the market they first have to become licensed which can take about a year. After that they are constantly being regulated by several organizations such as the Federal Aviation Administration and the Department of Transportation. The time and money spend to solely open an airline company is enough to prevent most people from entering the industry. Threat of Substitutes After looking at the threat of entry it is important to also consider the threat of substitutes. This industry has a medium substitute risk level. There are substitutes in the airline industry. Consumers can choose other form of transportation such as a car, bus, train, or boat to get to their destination. There is however a cost to switch. Some means of transportation can be more costly than a plane ticket. The main cost is time. Planes are by far the fastest form of transportation available. Airlines surpass all other forms of transportation when it comes to cost, convenience, and sometimes service. Consumers do sometimes choose other methods for various reasons such as cost if they are not traveling very far which raises the risk. Rivalry among Existing Players The last area of the five forces is the rivalry among existing players. The rivalry in the airline industry is very intense for many reasons. The industry is currently very stagnant. It seems to be in the mature stage of the business cycle. The number of competitors stays the same in the long run  and it doesn’t seem to be under or over capacitated. The fixed costs are extremely high in this industry. This makes it hard to leave the industry because they are probably in long term loan agreements in order to stay in business. The products involved or the planes are highly complex which also heightens the competition. The competition is lessened by the brand identities of different firms. For example, Jetblue is known for its amenities and Southwest is known for its low prices. The market share seemed to be equally distributed because each company has its own part of the market and because switching costs are low none of the firms can really hold a large percentage of the market. The strongest forces in this industry are the competition of existing firms and the power of suppliers. The rivalry of existing players is high and will push out any firm that doesn’t have enough capital. Suppliers are strong forces because planes are so costly to make. If the suppliers changed the credit terms by even a small amount it could mean a significant loss for the firm. On the other hand the other forces involved seem to have a weak threat. It is costly and time consuming to enter the market which lowers the risk of entry. Buyers have a weak force because of the low switching costs and substitutes are weak because they are usually too costly. The profit in this industry is high because for most people flying in necessary. It is not a trend which makes this industry profitable for the long term. Airlines that are more profitable are in a better position because they usually have more planes and a larger variety of flights which provides further convenience for the consumer. Recently there have been some changes in some of the forces. Some airplane manufacturers have been making ecofriendly planes, which is a change in the bargaining power of suppliers. This would differentiate the products, raising the threat of suppliers. Another recent change is the use of web portals such as Expedia to book flights. This positive change creates a whole new group of buyers and makes purchasing flights faster and easier. The increase in gas prices has also been a positive change for the industry  because it lessens the power of substitutes. People are more willing to fly to their destination if driving would be more expensive. After looking at the Five Forces Model firms should make dealing with the competition their main priority. The other areas in the model seem to have an overall low threat so existing firms don’t have to focus on those areas as much in their business strategy. Now that we have brought you through our Porter’s Five Force analysis, the last thing that is important to consider when exploring an industry, are the dominant economic features. The next section of our report will give you an overview of what features affect the airline industry most.

The Witchcraft Act Of 1604 - 1319 Words

In 1692, the paranoia of witchcraft being amongst them struck the puritan colony known as Salem Massachusetts with fear. More importantly, the belief in witchcraft was carried over from their home country, England. In England, an act of witchcraft was considered treason against the church, not to mention the king was the head of the church so turning your back on the church also meant going against the king. Many acts against witchcraft were passed, the one dated closest to the Salem witch trials was the Witchcraft Act of 1604 that moved trials of the supposed witches from churches to actual courts. The fact that they were once held in churches rather than courts seems like a biased situation to me. The puritans were afraid of witchcraft so having the church conduct the trials of said witches could only mean that death was certain. The puritan faith to my understanding was a tough faith to follow, especially for women. Gender roles were heavily put upon puritan women, â€Å"women were seen as inferior beings that needed to be dominated by a male figure, and those who broke the mold were viewed as dangerous.† When speaking of puritan women and church, women were not allowed to pray with the congregation or lead a prayer. The fact that women were viewed as â€Å"dangerous† should they not conform to their gender roles should really show just how ridiculous their belief system was. One can only imagine that the paranoia of women being witches derived from the belief that all womenShow MoreRelatedThe Truth Of Witchcraft And Witchcraft1519 Words   |  7 PagesMany question as to why so many women would eventually admit to witchcraft. However, it is quite understandable why these women accepted the guilt when analyzing the process of proving witchcraft and what these women had to endure. 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The Upside of Team Work - 847 Words

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Facing all these problems and bring them into work all these will done in team work. Facing all the things, avoiding domination, good communication, sharing of work will help to form good team to reach goals. Working in a team will totally different compare to doing individual work. Working with different people. Attitudes and communication all play a key role in team building. Members in the team will have different learning styles. First to settle in team it taken some time to understand each other. Firstly weShow MoreRelatedPolarity802 Words   |  4 Pagespolarities by realizing each opposite â€Å"pole† has an upside and a downside. The strategy is to identify the upsides of both poles and their downsides. Management should devise a plan that gives benefits of the upsides and avoids their respective downsides. (Ammann, 2008). Polarity management is not the final answer to conflicts; however, an important technique for working with continuing disputes. 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If I Do Not Possess Integrity, I Am No One Essays

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In each of these positions, one could beRead MoreStudent Leadership As A Student Leader704 Words   |  3 Pagesgrades- Substantial grades are essential to have before getting a leadership position. Being committed to grades is critical to becoming a student leader. Particularly since marching band will take up time after school, for example, homework time students do not need various activities overpowering themselves.Students need to conclude that together we can construct the band to be successful by being fully engaged. Passion for music- A passion for music will lead to significant outcomes for the band. Wanting

The Importance of Process Planning and Designing

Question: Discuss about The Importance of Process Planning and Designing. Answer: Process planning and designing is a wide concept and a key for success for any professional. Unplanned work leads to an unidentified path which yields nil results. Without planning and designing ones work, it is difficult to achieve the desired results within the specified time frame and limitations. Deciding upon the course of action required for the transformation of raw materials to finished products is termed as process planning. For achieving the output of a product as per the specified design, a series of planned operations have to be executed in a timely manner. The operations to be performed are both complex as well as simple in nature. More attention is required in the execution of complex processes as they take more time. As a marketer, it is very important for me to understand the present processes which are already in vogue and then suggest changes and modifications only after analysing the profits that the organization would be able to earn upon its implementation. Bring ing changes in the existing process is a very costly affair for any organization and it would have a direct impact on its brand image as well as the top line. Thus for a new entrant like me process planning and designing basically caters to transformation process i.e. the art of utilizing the current equipment and machinery for delivering ones own processes and designs. Companies favour those who try to do something new with the available resources, investing little into new equipments and machinery because of the cost factor. Process design in simpler terms can be defined as an operational chain with detailed progression stages to be performed so as to achieve the specification of the designs without compromising on the quality as well as the timely disposal of activities. These two are the most important factors that is to be considered along with ensuring to utilize the available resources in the most optimum manner so that production cost is also reduced. All this can be achieved only if proper integration is done between the human capital and the other resources. Machines cannot work on their own until and unless an input is given by the workers, thus a proper co-ordination between the two is of utmost importance. Trying to bring a revolutionary change into the current process of an established entity is the most challenging task. One has to first and foremost convince the management about the viability of the proposed changes with regards safety, brand building, timely conversion, production increase , cost benefit analysis, acceptability by the floor people as they are the ones who are directly attached to performances. It is very important to ensure that transformation within oneself and in the outside world is to be done gradually. It would seem very impracticable to expect that once a process has been planned and designed then it should be put to action instantly. The transformation process has to be given its own time to breathe. The most important segment of an organization is operations and its management. As a marketer it is to be understood by me that for introducing a change a study with regards the amount of value addition that it would do to ones personality, brands, customers to whom it will cater to finally and the cost factor from the companys view point has to be accounted for. Thus according to me transformation is easily identifiable and related with regards the conversion of raw materials but where transformation with regards any data or human capital is associated then the change is not evident enough to be noticeable. This makes it clear to me that expecting a sudden change to be visible to the organization at its very instance is not true. The change is gradual, however with regards any kind of product development change the result will be instantaneous. Similarly expecting a transformation in the behaviour of the customers and the internal staff at its very brim is false. Change in human nature may take place but its effect is gradual and hence adequate space has to be given for the same. Analysis of the results of implementation of a new process design and its transformed state has to be done by breaking the entire chain into smaller parts. It is only then I will be able to analyse the success parameters. Thus on a conclusive note I would like to bring to light that if I were to succeed both in profession as well as personal life, planning and designing of processes is of utmost importance. A pre-defined path and clarity in thoughts and processes will help to make this transformation easier. Before introducing change in any organization, the confidence of the people who would be a party of them is required to be won by making them a part of such a planning and designing process and welcoming their suggestions.

Peter Paul Rubens free essay sample

The most sought-after painter in northern Europe during the seventeenth century, Peter Paul Rubens, was also a diplomat, linguist, and scholar. His dramatic artistic style of the seventeenth century is now called baroque, a term apparently derived at a later time from ornate jewelry set with irregular pearls. At its most exuberant, the baroque involves restless motion, startling color contrasts, and vivid clashes of light and shadow. Rubens was born in Siegen, Westphalia, to Jan Rubens and Maria Pypelincks. Born the son of a lawyer and educated at a Jesuit school in Antwerp, Flanders, Rubens learned classical and modern languages. He spent the years 1600 to 1608 studying and working in Italy. Returning to Antwerp, he continued to travel as both courtier and painter. His repeated visits to Madrid, Paris, and London allowed him to negotiate treaties while accepting royal commissions for art. One of Rubens major innovations in procedure, which many later artists have followed, was his use of small oil studies as compositional sketches for his large pictures and tapestry designs. We will write a custom essay sample on Peter Paul Rubens or any similar topic specifically for you Do Not WasteYour Time HIRE WRITER Only 13.90 / page Rather than merely drawing, Rubens painted his modelli, or models, thereby establishing the color and lighting schemes and the distributions of shapes simultaneously. Rubens managed a very large studio in Antwerp, training many apprentices and employing independent colleagues to help execute specific projects. Among his mature collaborators whose baroque works are on view in the National Gallery of Art are Anthony van Dyck, Jacob Jordaens, Jan Brueghel, and Frans Snyders. Rubens style tremendously influenced baroque painters throughout Europe, even those such as the German-born Johann Liss who had no documented contact with the master. Liss The Satyr and the Peasant, for instance, is Rubensian in its lively gestures and telling expressions. Painted during the 1620s in Italy, it illustrates a tale from Aesops Fables in which an immortal satyr helped a peasant find his way through a winter storm. The goat-legged creature was astonished when the man put his chilled hands to his mouth to warm them. In thanks for the satyrs guidance, the peasant invited him home to eat. The satyr was further perplexed when the man blew on his spoon to cool the hot soup. The satyr jumped up in disgust at human hypocrisy, proclaiming, I will have nothing to do with someone who blows hot and cold with the same breath! The Fall of Man Rubens copied many of Titians paintings. Part of Rubens greatness was due to his eager study of earlier masters and his ability to combine their techniques with his own style. The Fall of Man is an interesting example of a work after Titian, that is very close to the original but in which Rubens has changed some details. The red parrot in the tree is not in Titians painting. The colors in Rubens painting are more yellowish and Rubens has actually improved Titians painting by giving Adam a more natural pose. In fact, Adam looks a lot like Rubens himself. When Rubens made this painting, he had just met his second wife-to-be, Helene Fourment. She was only 15 years old at the time. Adoration of the Magi Religious paintings were fashionable during the time of Peter Paul Rubens and were nearly always reverential. Adoration of the Magi is a good example of how Jesus was expected to be venerated in art. A painting of 99 inches by 133 inches, Adoration of the Magi is an oil on canvas painting that features a group of figures, who are waiting in turn to pay homage to the newly born Jesus. It is painting that was created by Rubens in 1616 and 1617. The Power of Christ The Virgin Mary is depicted holding up Jesus as an elderly magus kisses the babys feet. Rubens clearly shows that Jesus is no normal child, as quite apart from the large group of people who have come to see Christ, the infant Jesus is seen touching the head of the elderly magus as a sign of acknowledgment of the old mans devotion. Rubens also adds power to the image and of Jesus himself, with the ethnic mix of the visitors. This suggests that the men have traveled from many different parts of the world to witness seeing the baby Jesus and are not all, in fact, magi. The age of the men and the way they are dressed indicates men of power, and, consequently, their humble adoration of Christ gives the work an added weight. Though the expression of the figures in the painting are almost universally serious, there is one man who appears to be smiling and acts in a way many adults would normally act on seeing a baby. The Virgin Mary, however, looks very serious, almost severe, but she is concentrating on Jesus not coming to any harm, as he is standing upright to receive the line of visitors. The Propaganda Element As with most religious paintings of the early 17th Century there could be said to be an element of propaganda in Adoration of the Magi, as it is really showing the power of the Church. It is painting that is saying that however powerful leaders may be, the Church is more powerful than any earthly empire. The fact that there is little light in the painting gives it an air of mystery, as one wonders if some figures are deliberately hidden. Some of the visitors to the stable are also partly hidden by other visitors. The horse to the left of the painting infers that animals are also part of the kingdom of God. Adoration of the Magi currently hangs in the Musee des Beaux-Arts, Lyon, France. VENUS IN FRONT OF THE MIRROR Peter Paul Rubens presented his Venus in Front of the Mirror as the ultimate symbol of beauty. She is aware of the viewer in a mirror that frames her face like a portrait. Great play is made of the sensual reproduction of her skin and silky hair, which is further enlivened by the contrast with the dark-skinned maidservant. The few costly accessories, otherwise decorative additions to elaborate clothing, emphasize the figure’s nakedness. The sensual qualities of the painting are created by Rubens’s subtle painterly approach. He alternates sketchy brushstrokes, drawn over the ground like a transparent veil, with compact areas, painted in great detail. One particularly attractive feature of the picture is the contrast between the goddess’s encounter with the viewer, which seems to occur almost by chance, and the representation of her beauty, as if conceived for a spectator. The mirror that Cupid holds up for the goddess reveals an additional level of meaning: the reflection of Venus, which reveals her beauty to the viewer, becomes a symbol of painting that competes with nature to produce an image that is as real as possible.